\u6628\u65e5\u7d39\u4ecb\u3057\u305f3M\u793e\u306e\u96fb\u6c17\u5316\u5b66\u7684CO2\u9084\u5143\uff08CO\u3092\u3064\u304f\u308b\uff09\u306f\u3001\u96fb\u89e3\u6db2\u306b\u786b\u9178\u3068\u30a4\u30aa\u30f3\u6db2\u4f53\u3001\u9670\u6975\uff08CO2\u3092\u9084\u5143\u3059\u308b\u5074\uff09\u306b\u9280\u30ca\u30ce\u7c92\u5b50\u3001\u967d\u6975\uff08\u9178\u7d20\u767a\u751f\u5074\uff09\u306b\u767d\u91d1\u30ca\u30ce\u7c92\u5b50\u3092\u4f7f\u3063\u3066\u3044\u307e\u3059\u3002
\nCO2\u306f\u6c34\u7d20\u7d50\u5408\u3092\u4f5c\u308b\u3088\u3046\u306a\u5b98\u80fd\u57fa\uff08\u30a2\u30df\u30f3\u306a\u3069\uff09\u304c\u3042\u308b\u3068\u826f\u304f\u6eb6\u3051\u307e\u3059\u304c\u3001\u786b\u9178\u3092\u4f7f\u3063\u3066\u3044\u308b\u306e\u304c\u65ac\u65b0\u3067\u3059\u3002\u786b\u9178\u306b\u306fCO2\u304c\u6eb6\u3051\u306b\u304f\u3044\u306e\u3067\u6eb6\u304b\u3059\u305f\u3081\u306b\u30a4\u30aa\u30f3\u6db2\u4f53\u3092\u4f7f\u3063\u3066\u3044\u308b\u306e\u304b\u3082\u3057\u308c\u307e\u305b\u3093\u3002
\nAg\u3092\u89e6\u5a92\u306b\u4f7f\u3063\u3066\u3044\u308b\u306e\u304c\u9762\u767d\u3044\u3067\u3059\u3002\u660e\u65e5\u7d39\u4ecb\u3059\u308b\u53c2\u8003\u66f8\u3067Ag\u3092\u89e6\u5a92\u306b\u4f7f\u3046\u4f8b\u304c\u306a\u3044\u304b\u8abf\u3079\u307e\u3057\u305f\u304c\u3001CO2\u306e\u6c34\u7d20\u6dfb\u52a0\u306b\u4f7f\u3063\u3066\u3044\u308b\u6587\u732e\u304c\uff11\u3064\u3042\u308b\u3060\u3051\u3067\u3001\u305d\u308c\u307b\u3069\u3042\u308a\u3075\u308c\u305f\u53cd\u5fdc\u3067\u306f\u306a\u3044\u3088\u3046\u3067\u3059\u3002
\n\u9084\u5143\u5074\u3067\u4f7f\u3063\u3066\u3044\u308b\u306e\u3067\u9280\u30ca\u30ce\u7c92\u5b50\u306f\u6eb6\u3051\u305f\u308a\u306f\u3057\u3066\u3044\u306a\u3044\u3068\u601d\u3044\u307e\u3059\u3002\u3069\u3046\u3044\u3046\u4ed5\u7d44\u307f\u304b\u4e0d\u601d\u8b70\u306b\u601d\u3063\u3066\u8abf\u3079\u305f\u3068\u3053\u308d\u3001\u305f\u304f\u3055\u3093\u5f15\u7528\u3055\u308c\u3066\u3044\u308b
\nhttps:\/\/pubs.acs.org\/doi\/10.1021\/jp310509z
\n\u304c\u898b\u3064\u304b\u308a\u307e\u3057\u305f\u3002Ag\u30ca\u30ce\u7c92\u5b50\u306e\u5927\u304d\u3055\u304c5nm\u306e\u3068\u304d\u306f\u30d0\u30eb\u30af\u8868\u9762\u3088\u308a\u308210\u500d\u6d3b\u6027\u304c\u9ad8\u304f\u30011nm\u306e\u6642\u306f\u6d3b\u6027\u304c\u306a\u304f\u306a\u308b\u3068\u306e\u3053\u3068\u3002\u4e2d\u9593\u4f53\u306e\u5438\u7740\u304c\u52b9\u3044\u3066\u3044\u308b\u306e\u3060\u308d\u3046\u3001\u3068\u3044\u3046\u3053\u3068\u3067\u3059\u3002
\n\u3053\u306e\u8ad6\u6587\u3067\u306f\u3001\u4e2d\u9593\u4f53\u306f\u3000EMIM^+(l) + CO2(g) + e^- \u2192\u3000complex(ad)\u3000\u3067\u3042\u3089\u308f\u3055\u308c\u308b complex(ad) \u3068\u3055\u308c\u3066\u3044\u307e\u3059\u3002EMIM^+\u306f\u4f7f\u3063\u3066\u3044\u308b\u30a4\u30aa\u30f3\u6db2\u4f53\u306e\u967d\u30a4\u30aa\u30f3\u3067\u3059\u3002\u306a\u305c\u5438\u7740\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u30ca\u30ce\u7c92\u5b50\u30b5\u30a4\u30ba\u306b\u4f9d\u5b58\u3059\u308b\u304b\u306f\u3001\u8a08\u7b97\u3092\u5f85\u3061\u305f\u3044\u3068\u306e\u3053\u3068\u3067\u3001\u3053\u308c\u304c2013\u5e74\u3067\u3059\u3002\u305d\u306e\u5f8c\u3069\u3046\u306a\u3063\u305f\u3067\u3057\u3087\u3046\u304b\u3002<\/p>\n
\u82f1\u8a9e\u306f \u3053\u306e\u8ad6\u6587\u304b\u3089\u62fe\u3063\u3066\u307f\u307e\u3059\u3002\u4eca\u56de\u306f\u3044\u308d\u3044\u308d\u5207\u7fbd\u8a70\u307e\u3063\u3066\u3044\u3066\u3001\u30ac\u30c1\u306e\u5316\u5b66\u306e\u8a71\u3067\u3059\u307f\u307e\u305b\u3093\u3002
\nenhanced activity \u5f37\u5316\u3055\u308c\u305f\u6d3b\u6027
\n“We attribute this effect to a volcano effect associated with changes of the binding energy of key intermediates as the particle size decreases.”
\nattribute \uff5e\u306b\u5e30\u3059\u308b\u3001\uff5e\u306e\u3082\u306e\u3060\u3068\u3059\u308b
\nvolcano effect \u706b\u5c71\u578b\u306e\u52b9\u679c\uff08\u4f55\u304b\u306e\u5909\u6570\u3092\u7cfb\u7d71\u7684\u306b\u5909\u5316\u3055\u305b\u305f\u3068\u304d\u306b\u771f\u3093\u4e2d\u304c\u9ad8\u3044\u6027\u80fd\u3092\u793a\u3059\u3053\u3068\uff09\u3000\u30f4\u30a9\u308b\u300c\u30b1\u30a4\u300d\u30ce
\nassociated with \uff5e\u306b\u95a2\u9023\u3059\u308b
\nbinding energy \u7d50\u5408\u30a8\u30cd\u30eb\u30ae\u30fc
\nkey intermediate \u9375\u3068\u306a\u308b\u4e2d\u9593\u4f53
\nsulfric acid \u786b\u9178
\nelectrolyte \u96fb\u89e3\u6db2
\ncatholyte and anolyte \u9670\u6975\u96fb\u89e3\u6db2\u3068\u967d\u6975\u96fb\u89e3\u6db2
\n“The explanation for these different effects is not obvious.” \u3053\u308c\u3089\u306e\u7570\u306a\u3063\u305f\u52b9\u679c\u306e\u8aac\u660e\u306f\u3059\u3050\u306b\u308f\u304b\u308b\u3082\u306e\u3067\u306f\u306a\u3044\u3002 obvious \u300c\u30aa\u300d\u30d6\u30f4\u30a3\u30a2\u30b9\u3000\u660e\u78ba\u306a\u3001\u660e\u5feb\u306a\u3001\u3059\u3050\u306b\u308f\u304b\u308b<\/p>\n","protected":false},"excerpt":{"rendered":"
\u6628\u65e5\u7d39\u4ecb\u3057\u305f3M\u793e\u306e\u96fb\u6c17\u5316\u5b66\u7684CO2\u9084\u5143\uff08CO\u3092\u3064\u304f\u308b\uff09\u306f\u3001\u96fb\u89e3\u6db2\u306b\u786b\u9178\u3068\u30a4\u30aa\u30f3\u6db2\u4f53\u3001\u9670\u6975\uff08CO2\u3092\u9084\u5143\u3059\u308b\u5074\uff09\u306b\u9280\u30ca\u30ce\u7c92\u5b50\u3001\u967d\u6975\uff08\u9178\u7d20\u767a\u751f\u5074\uff09\u306b\u767d\u91d1\u30ca\u30ce\u7c92\u5b50\u3092\u4f7f\u3063\u3066\u3044\u307e\u3059\u3002 CO2\u306f\u6c34\u7d20\u7d50\u5408\u3092\u4f5c\u308b\u3088\u3046\u306a\u5b98\u80fd\u57fa\uff08\u30a2\u30df\u30f3\u306a\u3069\uff09\u304c\u3042\u308b\u3068\u826f\u304f\u6eb6\u3051\u307e\u3059\u304c\u3001\u786b\u9178\u3092\u4f7f\u3063\u3066\u3044\u308b\u306e\u304c\u65ac\u65b0\u3067\u3059\u3002\u786b\u9178\u306b\u306fCO2\u304c\u6eb6\u3051\u306b\u304f\u3044\u306e\u3067\u6eb6\u304b\u3059\u305f\u3081\u306b\u30a4\u30aa\u30f3\u6db2\u4f53\u3092\u4f7f\u3063\u3066\u3044\u308b\u306e\u304b\u3082\u3057\u308c\u307e\u305b\u3093\u3002 Ag\u3092\u89e6\u5a92\u306b\u4f7f\u3063\u3066\u3044\u308b\u306e\u304c\u9762\u767d\u3044\u3067\u3059\u3002\u660e\u65e5\u7d39\u4ecb\u3059\u308b\u53c2\u8003\u66f8\u3067Ag\u3092\u89e6\u5a92\u306b\u4f7f\u3046\u4f8b\u304c\u306a\u3044\u304b\u8abf\u3079\u307e\u3057\u305f\u304c\u3001CO2\u306e\u6c34\u7d20\u6dfb\u52a0\u306b\u4f7f\u3063\u3066\u3044\u308b\u6587\u732e\u304c\uff11\u3064\u3042\u308b\u3060\u3051\u3067\u3001\u305d\u308c\u307b\u3069\u3042\u308a\u3075\u308c\u305f\u53cd\u5fdc\u3067\u306f\u306a\u3044\u3088\u3046\u3067\u3059\u3002 \u9084\u5143\u5074\u3067\u4f7f\u3063\u3066\u3044\u308b\u306e\u3067\u9280\u30ca\u30ce\u7c92\u5b50\u306f\u6eb6\u3051\u305f\u308a\u306f\u3057\u3066…<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"om_disable_all_campaigns":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[42,44],"tags":[5,7],"class_list":["post-1881","post","type-post","status-publish","format-standard","hentry","category-tech","category-materials","tag-tech","tag-materials"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=\/wp\/v2\/posts\/1881","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1881"}],"version-history":[{"count":0,"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=\/wp\/v2\/posts\/1881\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1881"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1881"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.sekaiken.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1881"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}